Counterions Control Whether Self-Assembly Leads to Formation of Stable and Well-Defined Unilamellar Nanotubes or Nanoribbons and Nanorods

Autor:	George Sfintes, Jens B. Simonsen, Erling Thyrhaug, Dong Shi, Christian Schwall, Bo W. Laursen, Peter Hammershøj, Marité Cárdenas
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Aqueous solution Nanostructure Organic Chemistry Inorganic chemistry General Chemistry Catalysis Carbenium ion chemistry.chemical_compound chemistry Chemical engineering Amphiphile Nanorod Self-assembly Counterion Well-defined
Zdroj:	Chemistry - A European Journal. 20:6853-6856
ISSN:	0947-6539
DOI:	10.1002/chem.201402523
Popis:	Self-assembly of the amphiphilic π-conjugated carbenium ion ATOTA-1(+) in aqueous solution selectively leads to discrete and highly stable nanotubes or nanoribbons and nanorods, depending on the nature of the counterion (Cl(-) vs. PF6(-), respectively). The nanotubes formed by the Cl(-) salt illustrate an exceptional example of a structural well-defined (29±2 nm in outer diameter) unilamellar tubular morphology featuring π-conjugated functionality and high stability and flexibility, in aqueous solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3d6c0b8ecf670d783aafeb1a9f0795e1 https://doi.org/10.1002/chem.201402523 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.