Octamethylferrocenylethynyl units as peripheral groups in rigid, pi-conjugated molecular architectures
| Autor: | Birgit Kleinebekel, Peter Jutzi |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 1997 |
| Předmět: |
chemistry.chemical_classification
Organic Chemistry ferrocene Alkyne chemistry.chemical_element Conjugated system Photochemistry Electrochemistry Biochemistry Copper Characterization (materials science) Inorganic Chemistry chemistry.chemical_compound chemistry Ferrocene electrochemistry Polymer chemistry Materials Chemistry alkyne multimetallic assembly Physical and Theoretical Chemistry Benzene |
| Popis: | The synthesis and full characterization of octamethylethynylferrocene 2 is described. Additionally, the reaction of 2 with copper(II) acetate, 1,4-diiodobenzene and 1,3,5-triiodobenzene to give 1.4-bis(octamethylferrocenyl)butadiyne 3, 1,4-bis(octamethylferroceny lethynyl)benzene 4 and 1,3,5-tris(octamethyferrocenyllethyny)be 5 is presented. As a result of electrochemical investigations of 2-5 only 3 shows two one-electron oxidations with a peak-separation of 150 mV. (C) 1997 Elsevier Science S.A. |
| Databáze: | OpenAIRE |
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