The simplest alkynyl thiocyanate HCCSCN and its isomers
| Autor: | Xiaoqing Zeng, Lina Wang, Bo Lu, Bifeng Zhu, Zhuang Wu, Guntram Rauhut |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Thiocyanate
Photoisomerization Isocyanide Metals and Alloys General Chemistry Medicinal chemistry Thioketene Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Yield (chemistry) Isothiocyanate Materials Chemistry Ceramics and Composites |
| Zdroj: | Chemical communications (Cambridge, England). 57(27) |
| ISSN: | 1364-548X |
| Popis: | The simplest alkynyl thiocyanate HCCSCN has been synthesized and characterized for the first time. HCCSCN is surprisingly stable at room temperature but undergoes photoisomerization in an Ar-matrix (10 K) to yield the novel sulfenyl isocyanide HCCSNC and thioketene NCC(H)CS. The isomeric isothiocyanate HCCNCS, missing in the photochemistry of HCCSCN, can be generated through the photodecarbonylation of propiolyl isothiocyanate. |
| Databáze: | OpenAIRE |
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