Poly(oxazoline) for the design of amphiphilic silicone coatings

Autor: Vincent Lapinte, Belkacem Tarek Benkhaled, Émilie Portier, Karine Réhel, Jean-François Bardeau, Fabrice Azemar, Isabelle Linossier, Fabienne Faÿ
Přispěvatelé: Institut des Molécules et Matériaux du Mans (IMMM), Le Mans Université (UM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Biotechnologie et Chimie Marines (LBCM), Université de Bretagne Sud (UBS)-Université de Brest (UBO)-Institut Universitaire Européen de la Mer (IUEM), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut Universitaire Européen de la Mer (IUEM), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Materials science
General Chemical Engineering
Context (language use)
macromolecular substances
02 engineering and technology
Oxazoline
engineering.material
[SPI.MAT]Engineering Sciences [physics]/Materials
03 medical and health sciences
chemistry.chemical_compound
Silicone
Coating
Amphiphile
PEG ratio
Materials Chemistry
[CHIM]Chemical Sciences
RTV silicone
ComputingMilieux_MISCELLANEOUS
0303 health sciences
Fouling
030306 microbiology
Organic Chemistry
technology
industry
and agriculture
021001 nanoscience & nanotechnology
[PHYS.PHYS.PHYS-GEN-PH]Physics [physics]/Physics [physics]/General Physics [physics.gen-ph]
Surfaces
Coatings and Films
chemistry
Chemical engineering
engineering
[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]
0210 nano-technology
Zdroj: Progress in Organic Coatings
Progress in Organic Coatings, Elsevier, 2021, 153, pp.106116. ⟨10.1016/j.porgcoat.2020.106116⟩
ISSN: 0300-9440
DOI: 10.1016/j.porgcoat.2020.106116⟩
Popis: Fouling release coatings are known to be ecofriendly and to be a good alternative to the coatings containing biocides. To improve their efficiency and lifespan the incorporation of additives seems required. Amphiphilic system as PEG-silicone coatings have a lower impact on the environment. However, PEG oxidation in seawater impacts its lifespan. In this context, the development and incorporation of new hydrophilic additives offers great potentiel. The objective of this study is to design an amphiphilic fouling release coating containing poly(oxazoline) (POx) as additives. POx have similar physical properties as PEG and have already been used in biomedical applications. POx with a trimethoxysilane end-group has been synthesized to be crosslinked in a RTV silicone coating. The impact of its incorporation in a PDMS coating has been evaluated on surface properties and on coating organization. The results have been compared with a similar PEG-silicone coating. In addition, microbiologic assays have been carried out to evaluate the bacterial adhesion and the fouling properties of the coating. Two biomedicals bacteria and a marine bacterium were used to confirm the interest of POx. POx-silicone coating showed similar fouling efficiency against bacteria as PEG-silicone coating despite a bigger surface roughness and a lower compatibility with PDMS.
Databáze: OpenAIRE
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