Chemistry of 2-Arylhydrazonals: Utility of Substituted 2-Arylhydrazono-3-Oxoalkanals as Precursors for 3-Oxoalkanonitriles, 3-Aminoisoxazole and 1,2,3- and 1,2,4-Triazoles

Autor: Osman M. E. El-Dusouqui, Mervat M. Abdelkhalik, Boby J. George, Mohammed Hilmy Elnagdi, Nouria A. Al-Awadi, Hicham H. Dib
Rok vydání: 2006
Předmět:
Zdroj: Journal of Chemical Research. 2006:295-302
ISSN: 2047-6507
1747-5198
DOI: 10.3184/030823406777410945
Popis: Efficient routes to 2-arylhydrazono-3-oxoalkanonitriles, 1,2,3- and 1,2,4-triazoles, and 3-aminoisoxazole utilising the oximes of the title hydrazones are reported. The behaviour of the oximes on pyrolysis in the gas phase and by flash vacuum is analysed. X-ray crystallography were used to confirm the structure of the triazole 10b and the 3-oxoalkanonitrile 12f.
Databáze: OpenAIRE