Soil dissipation of sugarcane billet seed treatment fungicides and insecticide using QuEChERS and HPLC

Autor: Darcey G. Wayment, Kylie A. Torres, Paul M. White, Harley J. Ledet
Rok vydání: 2021
Předmět:
Zdroj: Journal of Environmental Science and Health, Part B. 56:188-196
ISSN: 1532-4109
0360-1234
Popis: Chemical treatment of sugarcane seed with fungicides and insecticides prior to planting increases yields of cane and sugar for the perennial, annually harvested crop. However, the fate of the applied chemicals is unknown. Therefore, the purpose of this study was to measure the aerobic dissipation of selected billet seed treatment chemicals in a mineral sugarcane soil from Louisiana. Soil samples from the surface 15 cm were treated with either thiamethoxam, azoxystrobin, fluxapyroxad, propiconazole, or pyraclostrobin and monitored over 100 days under laboratory conditions. Insecticide and fungicide levels were determined by high performance liquid chromatography. Dissipation data were fitted to four kinetic models: simple first-order (SFO), first order multi-compartment (FOMC), double-first order in parallel (DFOP), and hockey-stick (HS). The dissipation half-life (DT
Databáze: OpenAIRE
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