Synthesis of a new bis(perfluoroalkyl oxirane) dioxyethylene ether

Autor:	Nejib Hussein Mekni, Hayet Khemis Medini, Ahmed Baklouti
Rok vydání:	2015
Předmět:	Bromine Epoxidation chemistry.chemical_element Mercuric acetate Dialkene ethers Dioxirane Bis(perfluoroalkylallyl) ethers Perfluoroalkyl oxirane chemistry.chemical_compound chemistry Dioxyethylene Ether Organic chemistry Ammonium chloride Phase-transfer catalyst
Zdroj:	Journal of Taibah University for Science. 9:564-569
ISSN:	1658-3655
DOI:	10.1016/j.jtusci.2014.10.001
Popis:	Classic direct synthetic methods failed to transform bis(perfluororalkylallyl) dioxyethylene ether into the corresponding bis(perfluoroalkyl oxirane). This transformation was instead realized using a mixture of mercuric acetate/bromine to produce the corresponding bromoacetate, which was subsequently transformed to a bromohydrin and further to bis(perfluoroalkyl oxirane) through the use of triethylbenzyl ammonium chloride as a phase transfer catalyst in alkaline media.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3cb8f46170eaff0b70335823a85a246d https://doi.org/10.1016/j.jtusci.2014.10.001 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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