Deoxybenzoin-containing polysulfones and polysulfoxides: Synthesis and thermal properties
| Autor: | Peter Deglmann, Abid Ali Mir, Todd Emrick, Sebastian Wagner, Roland Helmut Krämer |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Arylene Organic Chemistry Ether 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Step-growth polymerization chemistry.chemical_compound Monomer chemistry Polymer chemistry Materials Chemistry Organic chemistry Polysulfone Solubility 0210 nano-technology Flammability |
| Zdroj: | Polymer. 84:59-64 |
| ISSN: | 0032-3861 |
| DOI: | 10.1016/j.polymer.2015.12.031 |
| Popis: | Novel poly(arylene ether) sulfones, sulfoxides, and sulfides containing deoxybenzoin subunits were synthesized by step growth polymerization involving bishydroxydeoxybenzoin (BHDB) and the corresponding sulfur-containing monomers. The isolated polymers demonstrated good solubility in organic solvents, making them easily processible into transparent, flexible, and creasable films upon solution casting. All of the polymers prepared exhibited exceptionally low flammability characteristics, with total heat release (THR) values as low as 6 J/g-K, and char yield values as high as 54%. Inclusion of deoxybenzoin monomers into polysulfones with 4,4’-biphenyl led to heat release capacity (HRC) values less than half that of commercial polysulfones in use today, placing deoxybenzoin-based polysulfones and polysulfoxides into the ultra-low flammability category. |
| Databáze: | OpenAIRE |
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