Synthesis of Diruthenium μ-Chloromethylidyne Complex: C-C Bond Formation at the Bridging Carbon Atom via the Reduction of a μ-Chloromethylidyne Ligand

Autor:	Koichi Seki, Toshiro Takao
Jazyk:	angličtina
Rok vydání:	2021
Předmět:	Carbon atom Bridging (networking) 010405 organic chemistry Chemistry Ligand Organic Chemistry Bond formation 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Reduction (complexity) Crystallography Physical and Theoretical Chemistry
Zdroj:	Organometallics. 40(No. 4):467
Popis:	The μ-chloromethylidyne complex, [(Cp*RuCl)2(μ-CCl)(μ-Cl)] (2) (Cp* = η5-C5Me5), was prepared by the reaction of a triruthenium pentahydrido complex, [{Cp*Ru(μ-H)}3(μ3-H)2] (1), with CCl4. The reac...
Databáze:	OpenAIRE
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