Luminescent magnesium complexes with intra- and inter-ligand charge transfer

Autor:	Rohit Kumar, Sanjukta Pahar, Joy Chatterjee, Soumya Ranjan Dash, Rajesh G. Gonnade, Kumar Vanka, Sakya S. Sen
Rok vydání:	2022
Předmět:	Luminescence Molecular Structure Materials Chemistry Metals and Alloys Ceramics and Composites Magnesium General Chemistry Ligands Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England). 58(84)
ISSN:	1364-548X
Popis:	Herein, we report two 2,2'-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively. Theoretical calculations reveal that their emissive properties originate from the intra- and inter-ligand charge transfer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c1e837ba8cb0b84486de149827a31f9 https://pubmed.ncbi.nlm.nih.gov/36193808 Zobrazit plný text záznamu