Synthesis and Structural Characterization of Zn(O3PCH2OH), a New Microporous Zinc Phosphonate

Autor:	Benson M. Kariuki, Gary B. Hix, Maryjane Tremayne, Simon J. Kitchin
Rok vydání:	2001
Předmět:	Hydroxy group Metallurgy chemistry.chemical_element Zinc Microporous material Trigonal crystal system Medicinal chemistry Phosphonate Oxygen Inorganic Chemistry Hydrolysis chemistry.chemical_compound chemistry Octahedron Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 40:1477-1481
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic000943x
Popis:	Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R3, with a = 15.9701(2) A, c = 7.783(2) A, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c160406474f58ec112f9ab83b523fb7 https://doi.org/10.1021/ic000943x Zobrazit plný text záznamu