New Layered Polythiophene-Silica Composite Through the Self-Assembly and Polymerization of Thiophene-Based Silylated Molecular Precursors
| Autor: | Danielle Laurencin, Marie-José Zacca, Sébastien Clément, Ahmad Mehdi, Sébastien Richeter |
|---|---|
| Přispěvatelé: | University of Balamand - UOB (LIBAN), Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Polymers Pharmaceutical Science 02 engineering and technology Thiophenes 010402 general chemistry 01 natural sciences Article Analytical Chemistry Polymerization lcsh:QD241-441 chemistry.chemical_compound lcsh:Organic chemistry Drug Discovery Thiophene sol-gel Lamellar structure Physical and Theoretical Chemistry Bifunctional Sol-gel chemistry.chemical_classification Organic Chemistry hybrid material lamellar Polymer self-assembly [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology Silicon Dioxide polythiophene 0104 chemical sciences chemistry Chemical engineering Chemistry (miscellaneous) silica Molecular Medicine Polythiophene 0210 nano-technology Hybrid material Oxidation-Reduction |
| Zdroj: | Molecules Molecules, MDPI, 2018, ⟨10.3390/molecules23102510⟩ Molecules : A Journal of Synthetic Chemistry and Natural Product Chemistry Volume 23 Issue 10 Molecules, Vol 23, Iss 10, p 2510 (2018) |
| ISSN: | 1420-3049 |
| Popis: | A new layered hybrid polythiophene-silica material was obtained directly by hydrolysis and polycondensation (sol-gel) of a silylated-thiophene bifunctional precursor, and its subsequent oxidative polymerization by FeCl3. This precursor was judiciously designed to guarantee its self-assembly and the formation of a lamellar polymer-silica structure, exploiting the cooperative effect between the hydrogen bonding interactions, originating from the ureido groups and the &pi stacking interactions between the thiophene units. The lamellar structure of the polythiophene-silica composite was confirmed by X-ray powder diffraction (XRD) and transmission electron microscopy (TEM) analyses. The solid-state nuclear magnetic resonance (NMR), UV-Vis, and photoluminescence spectra unambiguously indicate the incorporation of polythiophene into the silica matrix. Our work demonstrates that using a polymerizable silylated-thiophene precursor is an efficient approach towards the formation of nanostructured conjugated polymer-based hybrid materials. |
| Databáze: | OpenAIRE |
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