The optical spectrum of HCSi

Autor:	D. Cossart, R. Cireasa, M. Vervloet
Rok vydání:	1998
Předmět:	Materials science Triatomic molecule Optical physics Ab initio chemistry.chemical_element Molecular physics Molecular electronic transition Spectral line Atomic and Molecular Physics and Optics Neon Nuclear magnetic resonance chemistry Rotational spectroscopy Emission spectrum
Zdroj:	The European Physical Journal D. 2:199-201
ISSN:	1434-6079 1434-6060
Popis:	A new emission band system has been observed in the gas phase at around 850 nm. This system correlates with absorption bands previously measured in a neon matrix and assigned to a triplet electronic transition of SiC. However, the gas phase bands display a clear doublet structure. Preliminary molecular parameters resulting from the rotational analysis of the (000) - (000) band coincide with the expected values obtained by a recently published ab initio calculation carried out on the HCSi radical. We conclude that both the gas phase and the neon matrix spectra originate from the HCSi radical which is here identified for the first time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c0e1cd51ccd4269781619563b0977c9 https://doi.org/10.1007/pl00021570 Zobrazit plný text záznamu Full text from SpringerLink