Electrocatalysis of chloroacetic acids (mono-, di- and tri-) at a C60-[dimethyl-(β-cyclodextrin)]2 and nafion chemically modified electrode

Autor:	Zhennan Gu, Min Wei, Nanqiang Li, Xihuang Zhou, Meixian Li
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Perchlorate chemistry Nafion Chloroacetic acids Inorganic chemistry Polymer chemistry Cyclic voltammetry Rotating disk electrode Acetonitrile Electrocatalyst Analytical Chemistry Chemically modified electrode
Zdroj:	Talanta. 53:1045-1052
ISSN:	0039-9140
DOI:	10.1016/s0039-9140(00)00600-7
Popis:	The C(60)-[dimethyl-(beta-cyclodextrin)](2) and nafion chemically modified electrode (CME) exhibits one electroreduction peak and two electro-oxidation peaks in a mixed solvent of water and acetonitrile (3:2, v/v) containing tetra-butylammonium perchlorate. The reduction of chloroacetic acids (mono-, di- and tri-) can be electrocatalyzed at this electrode, indicating that C(60)-[dimethyl-(beta-cyclodextrin)](2) is capable of mediating the electron transfer to chloroacetic acids. Values of the apparent catalytic rate constant, k, were determined by using the rotating-disk electrode (RDE).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3bde8639d50ee1b6dd21e4a363c3966a https://doi.org/10.1016/s0039-9140(00)00600-7 Zobrazit plný text záznamu Full Text from ScienceDirect