| Autor: |
Xin Chen, Nan Gao, Mingcheng Qian, Shuai Zhao, Xiang-Xiang Chen |
| Rok vydání: |
2021 |
| Předmět: |
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| Zdroj: |
The Journal of organic chemistry. 86(10) |
| ISSN: |
1520-6904 |
| Popis: |
The cyclopropanation reaction of 3-diazooxindoles with arenes was first accomplished using visible-light irradiation. A series of spiro[norcaradiene-7,3'-indolin]-2'-ones were synthesized for the first time in high yields and with excellent diastereoselectivities. The synthetic usefulness of this catalyst-free photochemical methodology is illustrated by the further controllable rearrangement and epoxidation reactions. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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