Synthesis, characterization of the luminescent lanthanide complexes with (Z)-4-(4-methoxyphenoxy)-4-oxobut-2-enoic acid
| Autor: | Ying Yang, Ya-Ping Gao, Tonghuan Liu, Guojian Duan |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
Lanthanide
Luminescence Magnetic Resonance Spectroscopy Spectrophotometry Infrared Rare earth Inorganic chemistry Luminescence spectra Ligands Lanthanoid Series Elements Mass Spectrometry Analytical Chemistry Fourier transform infrared spectroscopy Instrumentation Spectroscopy Molecular Structure Ligand Chemistry Phenyl Ethers Temperature Carbon-13 NMR Atomic and Molecular Physics and Optics Butyrates Crystallography Spectrometry Fluorescence Elemental analysis |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 69:427-431 |
| ISSN: | 1386-1425 |
| DOI: | 10.1016/j.saa.2007.04.017 |
| Popis: | (Z)-4-(4-Methoxyphenoxy)-4-oxobut-2-enoic acid and its solid rare earth complexes LnL3·2H2O (Ln = La, Eu, Tb) were synthesized and characterized by means of MS, elemental analysis, FTIR, 13C NMR and TG–DTA. The IR and 13C NMR results show that the carboxylic groups in the complexes coordinated to the rare earth ions in the form of a bidentate ligand, but the ester carboxylic groups have not taken part in the coordination. The luminescence spectra of Eu(III) and Tb(III) complexes in solid state were also studied. The strong luminescence emitting peaks at 616 nm for Eu(III) and 547 nm for Tb(III) can be observed, which could be attributed to the ligand has an enhanced effect to the luminescence intensity of the Eu and Tb. |
| Databáze: | OpenAIRE |
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