Management of Energy Conversion Processes in Membrane Systems
| Autor: | Kornelia M. Batko, Izabella Ślęzak-Prochazka, Andrzej Ślęzak, Wioletta M. Bajdur, Maria Włodarczyk-Makuła |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: |
Control and Optimization
Renewable Energy Sustainability and the Environment transport Peusner’s network thermodynamics mathematical modeling Energy Engineering and Power Technology Kr form of the Kedem–Katchalsky–Peusner equations free energy control method of energy flow porous media membrane transport phenomena Electrical and Electronic Engineering entropy Engineering (miscellaneous) Energy (miscellaneous) |
| Zdroj: | Energies Volume 15 Issue 5 Pages: 1661 |
| ISSN: | 1996-1073 |
| DOI: | 10.3390/en15051661 |
| Popis: | The internal energy (U-energy) conversion to free energy (F-energy) and energy dissipation (S-energy) is a basic process that enables the continuity of life on Earth. Here, we present a novel method of evaluating F-energy in a membrane system containing ternary solutions of non-electrolytes based on the Kr version of the Kedem–Katchalsky–Peusner (K–K–P) formalism for concentration polarization conditions. The use of this formalism allows the determination of F-energy based on the production of S-energy and coefficient of the energy conversion efficiency. The K–K–P formalism requires the calculation of the Peusner coefficients Kijr and Kdetr (i, j ∈ {1, 2, 3}, r = A, B), which are necessary to calculate S-energy, the degree of coupling and coefficients of energy conversion efficiency. In turn, the equations for S-energy and coefficients of energy conversion efficiency are used in the F-energy calculations. The Kr form of the Kedem–Katchalsky–Peusner model equations, containing the Peusner coefficients Kijr and Kdetr, enables the analysis of energy conversion in membrane systems and is a useful tool for studying the transport properties of membranes. We showed that osmotic pressure dependences of indicated Peusner coefficients, energy conversion efficiency coefficient, entropy and energy production are nonlinear. These nonlinearities were caused by pseudophase transitions from non-convective to convective states or vice versa. The method presented in the paper can be used to assess F-energy resources. The results can be adapted to various membrane systems used in chemical engineering, environmental engineering or medical applications. It can be used in designing new technologies as a part of process management. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
| Nepřihlášeným uživatelům se plný text nezobrazuje | K zobrazení výsledku je třeba se přihlásit. |