Facile Preparation of Mesoporous MCM-48 Containing Silver Nanoparticles with Fly Ash as Raw Materials for CO Catalytic Oxidation
| Autor: | Yonghong Chen, Bin Lin, Dong Tian, Xiaoyong Lu, Yihan Ling |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
silver nanoparticles
Materials science Nanoparticle 02 engineering and technology 010402 general chemistry 01 natural sciences Article Silver nanoparticle Catalysis Adsorption Desorption TJ1-1570 Mechanical engineering and machinery composite Electrical and Electronic Engineering Mobil Composition of Matter Mechanical Engineering 021001 nanoscience & nanotechnology CO oxidation 0104 chemical sciences fly ash MCM-48 Chemical engineering Catalytic oxidation Control and Systems Engineering 0210 nano-technology Mesoporous material |
| Zdroj: | Micromachines; Volume 12; Issue 7; Pages: 841 Micromachines Micromachines, Vol 12, Iss 841, p 841 (2021) |
| ISSN: | 2072-666X |
| DOI: | 10.3390/mi12070841 |
| Popis: | An environmentally friendly method was proposed to prepare mesoporous Mobil Composition of Matter No.48 (MCM-48) using fly ash as the silica source. Silver nanoparticles were infiltrated on MCM-48 facilely by an in situ post-reduction method and evaluated as an effective catalyst for CO oxidation. The as-prepared MCM-48 and Ag/MCM-48 nanoparticles were characterized by XRD, N2 adsorption/desorption, and TEM. Investigations by means of XPS for Ag/MCM-48 were performed in order to illuminate the surface composition of the samples. Studies revealed the strong influence of the loading of Ag nanoparticles on catalysts in the oxidation of CO. CO conversion values for Ag/MCM-48 of 10% and 100% were achieved at temperatures of 220 °C and 270 °C, respectively, indicating that the Ag-decorated MCM-48 catalyst is extremely active for CO oxidation. |
| Databáze: | OpenAIRE |
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