Well-Defined, Air-Stable (NHC)Pd(Allyl)Cl (NHC: N-Heterocyclic Carbene) Catalysts for the Arylation of Ketones
| Autor: | Romain F. Germaneau, Steven P. Nolan, Mihai S. Viciu |
|---|---|
| Rok vydání: | 2003 |
| Předmět: |
chemistry.chemical_classification
Reaction conditions Ketone Aryl Organic Chemistry Halide General Medicine Biochemistry Medicinal chemistry Coupling reaction Catalysis chemistry.chemical_compound chemistry Organic chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Well-defined Carbene Amination |
| Zdroj: | ChemInform. 34 |
| ISSN: | 1522-2667 0931-7597 |
| DOI: | 10.1002/chin.200313094 |
| Popis: | A number of palladium-N-heterocyclic carbene (NHC) complexes were found to be active catalysts for the arylation of ketones. A large number of substrates, both aryl halides and ketones, are compatible with the reaction conditions. The ketone arylation reactions are achieved with low catalyst loading in short reaction times using aryl chlorides and triflates as reactive partners. [reaction: see text] |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text