Methyl Methacrylate (MMA) Treatment of Empty Fruit Bunch (EFB) to Improve the Properties of Regenerated Cellulose Biocomposite Films
Autor: | Salmah Husseinsyah, Abdulkader M. Alakrach, Chew Li Li, Azlin Fazlina Osman, Nur Liyana Izyan Zailuddin, Awad A. Alrashdi |
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Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: |
Materials science
Polymers and Plastics Regenerated cellulose General Chemistry regenerated cellulose Article lcsh:QD241-441 chemistry.chemical_compound Crystallinity chemistry Chemical engineering lcsh:Organic chemistry Ultimate tensile strength Ionic liquid empty fruit bunch Thermal stability Cellulose Biocomposite Methyl methacrylate ionic liquid methyl methacrylate |
Zdroj: | Polymers, Vol 12, Iss 2618, p 2618 (2020) Polymers Volume 12 Issue 11 |
ISSN: | 2073-4360 |
Popis: | The empty fruit bunch (EFB) regenerated cellulose (RC) biocomposite films for packaging application were prepared using ionic liquid. The effects of EFB content and methyl methacrylate (MMA) treatment of the EFB on the mechanical and thermal properties of the RC biocomposite were studied. The tensile strength and modulus of elasticity of the MMA treated RC biocomposite film achieved a maximum value when 2 wt% EFB was used for the regeneration process. The treated EFB RC biocomposite films also possess higher crystallinity index. The morphology analysis indicated that the RC biocomposite film containing MMA treated EFB exhibits a smoother and more homogeneous surface compared to the one containing the untreated EFB. The substitution of the &ndash OH group of the EFB cellulose with the ester group of the MMA resulted in greater dissolution of the EFB in the ionic liquid solvent, thus improving the interphase bonding between the filler and matrix phase of the EF RC biocomposite. Due to this factor, thermal stability of the EFB RC biocomposite also successfully improved. |
Databáze: | OpenAIRE |
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