Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)–H bonds adjacent to a nitrogen atom
| Autor: | Kazuhiko Takai, Tetsuya Omura, Yoichiro Kuninobu, Masahito Murai |
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| Rok vydání: | 2015 |
| Předmět: |
Boron Compounds
Primary (chemistry) Molecular Structure Hydrogen Nitrogen Chemistry Ligand Metals and Alloys chemistry.chemical_element General Chemistry Rhenium Photochemistry Acceptor Medicinal chemistry Borylation Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Nitrogen atom Atom economy Materials Chemistry Ceramics and Composites Hydrogenation |
| Zdroj: | Chemical Communications. 51:4583-4586 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Rhenium-catalysed C(sp(3))-H bond borylation in the absence of any oxidant, hydrogen acceptor, or external ligand, with the generation of H2 as the sole byproduct is described. The transformation, which represents a rare example of rhenium-catalysed C(sp(3))-H bond functionalisation, features high atom efficiency and simple reaction conditions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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