Amine‐Tagged Fragmented Ligand Installation for Covalent Modification of MOF‐74

Autor:	Hyeonbin Ha, Junmo Seong, Seok Jeong, Seonghwan Lee, Myoung Soo Lah, Min Kim, Jaewoong Lim, Seung Bin Baek
Rok vydání:	2021
Předmět:	Denticity 010405 organic chemistry Ligand Metalation Chemistry fungi Solvothermal synthesis General Chemistry General Medicine 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Covalent bond Surface modification Metal-organic framework
Zdroj:	Angewandte Chemie. 133:9382-9386
ISSN:	1521-3757 0044-8249
Popis:	MOF-74 is one of the most explored metal-organic frameworks (MOFs), but its functionalization is limited to the dative post-synthetic modification (PSM) of the monodentate solvent site. Owing to the nature of the organic ligand and framework structure of MOF-74, the covalent PSM of MOF-74 is very demanding. Herein, we report, for the first time, the covalent PSM of amine-tagged defective Ni-MOF-74, which is prepared by de novo solvothermal synthesis by using aminosalicylic acid as a functionalized fragmented organic ligand. The covalent PSM of the amino group generates metal binding sites, and subsequent post-synthetic metalation with PdII ions affords the PdII -incorporated Ni-MOF-74 catalyst. This catalyst exhibits highly efficient, size-selective, and recyclable catalytic activity for the Suzuki-Miyaura cross-coupling reaction. This strategy is also useful for the covalent modification of amine-tagged defective Ni2 (DOBPDC), an expanded analogue of MOF-74.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3b04d7c72d3cc47aa8a4bd46f2ce76e1 https://doi.org/10.1002/ange.202100456 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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