Determination and dietary risk assessment of 284 pesticide residues in local fruit cultivars in Shanghai, China
Autor: | Lei Chen, Yao-Dan Zhang, Wen-Shuai Si, Zhou Changyan, Guoqing Shen, Bing Bai |
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Jazyk: | angličtina |
Rok vydání: | 2021 |
Předmět: |
China
Science Food Contamination 010501 environmental sciences 01 natural sciences Risk Assessment Mass Spectrometry Article Toxicology Dietary Exposure Limit of Detection Humans Shanghai china Cultivar 0105 earth and related environmental sciences Multidisciplinary Pesticide residue Dietary risk 010401 analytical chemistry Pesticide Residues Reproducibility of Results Pesticide 0104 chemical sciences Chemistry Risk factors Acute exposure Fruit Medicine Chromatography Liquid |
Zdroj: | Scientific Reports, Vol 11, Iss 1, Pp 1-11 (2021) Scientific Reports |
ISSN: | 2045-2322 |
Popis: | The presence of pesticide residues has become one of the main risk factors affecting the safety and quality of agro-food. In this study, a multi-residue method for the analysis of 284 pesticides in five local fruit cultivars in Shanghai was developed based on ultrahigh-performance liquid chromatography-quadrupole time-of-fight mass spectrometry (UPLC-QTOF/MS). The limits of determination and the limits of quantitation of pesticides were 0.6–10 and 2–30 µg/kg, respectively. A total of 44, 10, 10, 18, and 7 pesticides were detected in strawberries, watermelons, melons, peaches, and grapes, respectively. The pesticide levels in 95.0% of the samples were below the maximum residual limits (MRLs) prescribed by China, and in 66.2% of the samples below the EU MRLs. The dietary risk assessment study showed big differences in the chronic and acute exposure risk values among different Chinese consumer groups. Through fruit consumption, children/females showed higher exposure risks than adults/males. But both the risk values were less than 100%, indicating that potential dietary risk induced by the pesticides was not significant for Chinese consumers. Nevertheless, certain measures are needed for both growers and government in order to decrease the MRL-exceeding rate of pesticide residues and ensure the quality and safety of fruits for consumers. |
Databáze: | OpenAIRE |
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