Iron-Doped Cobalt Phosphide Nanohoops for Electroreduction of Nitrate to Ammonia

Autor:	Qing-Ling Hong, Ze-Nong Zhang, Xiao-Hui Wang, Shi-Bin Yin, Feng Shi, Shu-Ni Li, Yu Chen
Rok vydání:	2022
Předmět:	Inorganic Chemistry Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 61:14397-14402
ISSN:	1520-510X 0020-1669
Popis:	Heteroatom doping can effectively tune the electronic structure of an electrocatalyst to accelerate the adsorption/desorption of reaction intermediates, which sharply increases their intrinsic electroactivity. Herein, we successfully prepare iron (Fe)-doped cobalt phosphide (CoP) nanohoops (Fe/CoP NHs) with different Fe/Co atomic ratios as highly active electrocatalysts for the nitrate electrocatalytic reduction reaction (NIT-ERR). Electrochemical measurements reveal that appropriate Fe doping can improve the electroactivity of cobalt phosphide nanohoops for the NIT-ERR. In a 1 M KOH electrolyte, the Fe/CoP NHs with the optimized chemical composition can achieve an efficient ammonia (NH
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3a84d734800864b8ba38972460ecc992 https://doi.org/10.1021/acs.inorgchem.2c02257 Zobrazit plný text záznamu