1-butyl-3-methylimidazolium cobalt tetracarbonyl [bmim][Co(CO)4]: a catalytically active organometallic ionic liquid
Autor: | Paul J. Dyson, Tom Welton, Richard James Brown, David J. Ellis |
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Rok vydání: | 2002 |
Předmět: |
Inorganic chemistry
Metals and Alloys chemistry.chemical_element General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ion chemistry.chemical_compound Transition metal chemistry Ionic liquid Materials Chemistry Ceramics and Composites Salt metathesis reaction 1-butyl-3-methylimidazolium Cobalt |
Zdroj: | Chemical communications (Cambridge, England). (18) |
ISSN: | 1359-7345 |
Popis: | An ambient temperature liquid transition metal carbonyl anion has been prepared in a metathesis reaction between [bmim]Cl ([bmim]+ = 1-butyl-3-methylimidazolium cation) and Na[Co(CO)4]; the ionic liquid catalyses the debromination of 2-bromoketones. |
Databáze: | OpenAIRE |
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