Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods
Autor: | Abigail M. Fagan, Benjamin C. Steimle, Raymond E. Schaak |
---|---|
Rok vydání: | 2022 |
Předmět: | |
Zdroj: | Chemical communications (Cambridge, England). 58(27) |
ISSN: | 1364-548X |
Popis: | We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu |
Databáze: | OpenAIRE |
Externí odkaz: |