Single-Atom Cobalt Incorporated in a 2D Graphene Oxide Membrane for Catalytic Pollutant Degradation

Autor:	Xuanhao Wu, Kali Rigby, Dahong Huang, Tayler Hedtke, Xiaoxiong Wang, Myoung Won Chung, Seunghyun Weon, Eli Stavitski, Jae-Hong Kim
Rok vydání:	2021
Předmět:	Environmental Chemistry Environmental Pollutants Graphite Cobalt General Chemistry Catalysis
Zdroj:	Environmental Science & Technology. 56:1341-1351
ISSN:	1520-5851 0013-936X
DOI:	10.1021/acs.est.1c06371
Popis:	We introduce a new graphene oxide (GO)-based membrane architecture that hosts cobalt catalysts within its nanoscale pore walls. Such an architecture would not be possible with catalysts in nanoscale, the current benchmark, since they would block the pores or alter the pore structure. Therefore, we developed a new synthesis procedure to load cobalt in an atomically dispersed fashion, the theoretical limit in material downsizing. The use of vitamin C as a mild reducing agent was critical to load Co as dispersed atoms (Co
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::39e1195ccb63c53cd0a9abeb40877df5 https://doi.org/10.1021/acs.est.1c06371 Zobrazit plný text záznamu