Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities

Autor: Bastien Michelet, Agnès Martin‐Mingot, Jean Rodriguez, Sébastien Thibaudeau, Damien Bonne
Přispěvatelé: Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), Université de Poitiers-Institut national des sciences de l'Univers (INSU - CNRS)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Aix Marseille Université (AMU), Institut des Sciences Moléculaires de Marseille (ISM2), Aix Marseille Université (AMU)-École Centrale de Marseille (ECM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Chemistry-A European Journal
Chemistry-A European Journal, In press, ⟨10.1002/chem.202300440⟩
ISSN: 0947-6539
1521-3765
Popis: International audience; Since the pioneer reports of Akiyama and Terada groups on Brønsted acid organocatalysis, this field never stopped growing with the development of ingenious strategies for the activation of challenging poorly reactive substrates. The development of superacidic organocatalysts is an important way to selectively functionalize reluctant electrophiles and other approaches have also emerged such as the combination of Lewis and Brønsted acids as well as the consecutive organocatalysis and superacid activation. This concept aims to highlight these different strategies and demonstrate their complementarity.
Databáze: OpenAIRE