Synthesis, characterization and catalytic activity in Suzuki-Miyaura coupling of palladacycle complexes with n-butyl-substituted N-heterocyclic carbene ligands
| Autor: | Rukiye Fırıncı, M. Emin Günay, Aytaç Gürhan Gökçe |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Chemistry Aryl Dimer chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Coupling reaction 3. Good health 0104 chemical sciences Dimethylbenzylamine Inorganic Chemistry chemistry.chemical_compound Transmetalation Organic chemistry Phenylboronic acid Carbene Palladium |
| Popis: | A series of monomeric palladacycle complexes bearing n-butyl-substituted N-heterocyclic carbenes, namely [Pd(NHC)X(dmba)] (dmba: dimethylbenzylamine and [Pd(NHC)X(ppy)]; NHC: 1-n-butyl-3-substituted benzylimidazol-2-ylidene; ppy: 2-phenylpyridine), were prepared either by transmetallation from the corresponding silver carbene complexes or by the reaction of the corresponding acetate-bridged palladacycle dimer with N-heterocyclic carbene ligands in high yields. The palladium(II) complexes were characterized using elemental analyses, APCI-MS, H-1 NMR and C-13 NMR spectroscopies. These complexes are efficient in the Suzuki-Miyaura coupling reaction between phenylboronic acid and aryl bromides. |
| Databáze: | OpenAIRE |
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