Resolvable polymorphism in an intergrowth of two modifications of tris(diethyldithiocarbamato)antimony
| Autor: | Seik Weng Ng |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Tris
chemistry.chemical_element Crystal structure Triclinic crystal system Condensed Matter Physics Inorganic Chemistry Bipyramid Crystallography chemistry.chemical_compound Antimony chemistry Polymorphism (materials science) Phase (matter) Materials Chemistry Physical and Theoretical Chemistry Monoclinic crystal system |
| Zdroj: | Acta Crystallographica Section C Structural Chemistry. 77:610-614 |
| ISSN: | 2053-2296 |
| DOI: | 10.1107/s205322962100886x |
| Popis: | Tris(diethyldithiocarbamato-κS)antimony(III), [Sb(C5H10NS2)3], is tentatively presumed to comprise a triclinic and a monoclinic polymorph intergrown into each other. The geometry in the triclinic phase is a ψ-capped octahedron and that in the monoclinic phase is a ψ-pentagonal bipyramid. The study also identifies the polyhedral symbols for a reported pair of polymorphs of another SbIII coordination compound, as well as for those of published polymorphic modifications of other BiIII and PbII coordination compounds; the symbols in the pair differ in most of these examples. When differentiating related structures of such classes of coordination compounds, lone-pair stereochemistry may be another informative variable, as stereochemical activity is not always apparent from bond distances and angles only. |
| Databáze: | OpenAIRE |
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