Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane uptake

Autor:	Hong-Cai Zhou, Daofeng Sun, Daqiang Yuan, Jason M. Simmons, Shengqian Ma, Christopher D. Collier
Rok vydání:	2008
Předmět:	Anthracene Langmuir Inorganic chemistry Analytical chemistry General Chemistry Microporous material Biochemistry Catalysis Methane chemistry.chemical_compound Colloid and Surface Chemistry Adsorption chemistry Metal-organic framework Nanoscopic scale Derivative (chemistry)
Zdroj:	Journal of the American Chemical Society. 130(3)
ISSN:	1520-5126
Popis:	A microporous metal-organic framework, PCN-14, based on an anthracene derivative, 5,5‘-(9,10-anthracenediyl)di-isophthalate (H4adip), was synthesized under solvothermal reaction conditions. X-ray single crystal analysis revealed that PCN-14 consists of nanoscopic cages suitable for gas storage. N2-adsorption studies of PCN-14 at 77 K reveal a Langmuir surface area of 2176 m2/g and a pore volume of 0.87 cm3/g. Methane adsorption studies at 290 K and 35 bar show that PCN-14 exhibits an absolute methane-adsorption capacity of 230 v/v, 28% higher than the DOE target (180 v/v) for methane storage.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3994fe45c33f80606d04505856a6d2df https://pubmed.ncbi.nlm.nih.gov/18163628 Zobrazit plný text záznamu