Multiple functional groups in UiO-66 improve chemical warfare agent simulant degradation
| Autor: | Seth M. Cohen, Mark Kalaj, Joseph M. Palomba, Kyle C. Bentz |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Catalytic degradation
Ligands 010402 general chemistry 01 natural sciences Catalysis Nitrophenols Organophosphorus Compounds Materials Chemistry Chemical Warfare Agents Particle Size Metal-Organic Frameworks 010405 organic chemistry Chemistry Ligand Single component fungi Metals and Alloys General Chemistry Mixed ligand Combinatorial chemistry 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Microscopy Electron Scanning Ceramics and Composites Degradation (geology) Particle size |
| Zdroj: | Chemical Communications. 55:5367-5370 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c9cc02252j |
| Popis: | A library of 26 mixed ligand UiO-66 analogs was synthesized, characterized, and screened for catalytic degradation of the chemical warfare agent (CWA) simulant dimethyl 4-nitrophenylphosphate (DMNP). The MOFs were screened and compared to physical mixtures of the same single component MOFs. Several of the MOFs display higher catalytic activity than the parent UiO-66 and other single ligand UiO-66 analogues. |
| Databáze: | OpenAIRE |
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