Directed Functionalization of Cyano-Substituted Furans and Thiophenes with TMPMgCl·LiCl

Autor:	Ricardo Vessecchi, Fernanda Santos, João H. C. Batista, Giuliano C. Clososki
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Nitrile Chemistry Metalation Furan Organic Chemistry Electrophile COMPOSTOS AROMÁTICOS Thiophene Surface modification TMPMgCl.LiCl Organic chemistry
Zdroj:	Repositório Institucional da USP (Biblioteca Digital da Produção Intelectual) Universidade de São Paulo (USP) instacron:USP
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0035-1560586
Popis:	A number of novel difunctionalized furans and thiophenes has been prepared by the reaction of the cyano-substituted substrates with TMPMgCl·LiCl followed by the reaction with electrophiles. The crucial metalation step takes place under mild conditions allowing the isolation of desired derivatives in reasonable to good yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::394087e3719ad8f41b2b428a751e799a https://doi.org/10.1055/s-0035-1560586 Zobrazit plný text záznamu