A Highly Dynamic Covalent Polymer Network without Creep: Mission Impossible?

Autor:	Filip Van Lijsebetten, Tapas Debsharma, Johan M. Winne, Filip E. Du Prez
Rok vydání:	2022
Předmět:	VITRIMERS Fast Reprocessing Creep Resistance VISCOELASTICITY CHEMICAL-STRUCTURE TRANSALKYLATION Dynamic Covalent Networks General Medicine General Chemistry Catalysis CROSS-LINK DENSITY Chemistry Recyclable Thermoset INTERNAL CATALYSIS ADAPTABLE NETWORKS EXCHANGE PHASE-SEPARATION
Zdroj:	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN:	1521-3773 1433-7851
Popis:	Dynamic covalent polymer networks provide an interesting solution to the challenging recyclability of thermosets and elastomers. One of the remaining design constraints, however, is balancing thermal reprocessability in the form of material flow with dimensional stability during use. As a result, many chemistries are being investigated in order to improve bond reactivity control and material robustness. This Minireview highlights a number of promising concepts, with a particular emphasis on disconnecting chemical reactivity in low and high temperature regimes to obtain creep resistant, yet highly dynamic polymer networks. In addition, we will highlight the impact of sharp reactivity changes when applying extrapolation-based approaches during rheological analysis. As a result, we are confident that abandoning the myth of "permanent" reactivity will aid in the development of sustainable polymeric materials that can truly combine the benefits of thermoplastic and thermoset behaviour.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::392675e9c270129ac0c58c1b9bed8e5f https://pubmed.ncbi.nlm.nih.gov/36161440 Zobrazit plný text záznamu Plný text