Characterization of a TiCl_{4}$-modified silica surface by means of quantitative surface analysis

Autor:	Koen Schrijnemakers, Pascal Van Der Voort, Etienne F. Vansant
Jazyk:	angličtina
Rok vydání:	1999
Předmět:	Surface (mathematics) Denticity Silica gel Relative distribution Analytical chemistry General Physics and Astronomy Characterization (materials science) chemistry.chemical_compound chemistry Elemental analysis Physical chemistry Physical and Theoretical Chemistry Photoacoustic spectroscopy Ftir pas
Zdroj:	Physical chemistry, chemical physics
ISSN:	1463-9076
Popis:	The reaction of TiCl4 with the surface of a silica gel has been investigated in detail using Fourier-transform IR photoacoustic spectroscopy (FTIR PAS) and elemental analysis. The hydroxy groups on the silica react with the TiCl4 giving rise to both monodentate and didentate surface groups. The parameters influencing the relative distribution of these groups have been studied. A quantitative description of the chemisorbed species has been obtained as a function of the pretreatment and the reaction temperatures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::39100a7ca711a6fe68ad45f45655d8d9 https://hdl.handle.net/10067/236200151162165141 Zobrazit plný text záznamu