Ru–Co Pair Sites Catalyst Boosts the Energetics for the Oxygen Evolution Reaction

Autor: Xiaobo Zheng, Jiarui Yang, Zhongfei Xu, Qishun Wang, Jiabin Wu, Erhuan Zhang, Shixue Dou, Wenping Sun, Dingsheng Wang, Yadong Li
Rok vydání: 2022
Předmět:
Zdroj: Angewandte Chemie. 134
ISSN: 1521-3757
0044-8249
DOI: 10.1002/ange.202205946
Popis: Manipulating the coordination environment of the active center via anion modulation to reveal tailored activity and selectivity has been widely achieved, especially for carbon-based single-atom site catalysts (SACs). However, tuning ligand fields of the active center by single-site metal cation regulation and identifying the effects on the resulting electronic configuration is seldom explored. Herein, we propose a single-site Ru cation coordination strategy to engineer the electronic properties by constructing a Ru/LiCoO
Databáze: OpenAIRE