Structure determination of a novel metal-organic compound synthesized from aluminum and 2,5-pyridinedicarboxylic acid
| Autor: | Bastian Brink, Kenny Ståhl, Jonas Lohmann Elkjær Andersen |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Radiation Metal-organic framework Inorganic chemistry Triclinic crystal system Condensed Matter Physics XRPD Organic compound Metal Crystallography chemistry.chemical_compound chemistry Octahedron visual_art visual_art.visual_art_medium Hydrothermal synthesis Hydroxide General Materials Science 2 5-pyridinedicarboxylic acid Instrumentation Powder diffraction Aluminum |
| Zdroj: | Ståhl, K, Brink, B & Andersen, J 2011, ' Structure determination of a novel metal-organic compound synthesized from aluminum and 2,5-pyridinedicarboxylic acid ', Powder Diffraction, vol. 26, no. S1, pp. S44-S46 . https://doi.org/10.1154/1.3659288 |
| DOI: | 10.1154/1.3659288 |
| Popis: | The structure of [Al2(pydc)2(μ2-OH)2(H2O)2]n(pydc = 2,5-pyridinedicarboxylate) was successfully determined from powder X-ray diffraction data. The compound crystallizes in the triclinic system (space group P -1) with a = 6.7813(1) Å, b = 7.4944(1) Å, c = 8.5013(1) Å, α = 95.256(1)°, β = 102.478(1)°, γ = 108.979(1)°. The structure consists of aluminum ions coordinating N and O in distorted octahedra, sharing an edge through two hydroxide ions. These dinuclear complexes are connected by pydc ions, which at one end coordinate by nitrogen and oxygen and only by oxygen at the other end. The pydc orientation is reversed in the neighboring pydc, forming double stranded chains interconnected by the aluminum dinuclear complexes in a ladder-like arrangement along [001]. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|