Calculation of Aqueous Solubility of Organic Compounds

Autor:	Michele M. Miller, Yadu D. Tewari, Stanley P. Wasik
Rok vydání:	2021
Předmět:	Partition coefficient Volume measurements Octanol Activity coefficient Hildebrand solubility parameter chemistry.chemical_compound Chemistry Aqueous solubility General Engineering Analytical chemistry Gas chromatography Dilution Physics and Chemistry
Zdroj:	J Res Natl Bur Stand (1977)
ISSN:	0160-1741
Popis:	The aqueous solubility of 14 organic solutes has been calculated from their octanoL/water partition coefficient and from their solute activity coefficient in octanol at infinite dilution. The solute activity coefficients were calculated from the Flory-Huggins and Hildebrand-Scatchand (FH-HS) equations and were found to be in good agreement with the activity coefficients detennined from GC specific retention volume measurements. The calculated solubilities were in good agreement with the experimental solubilities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::38efdeeabb68fc66ff930eb3701e1d61 https://pubmed.ncbi.nlm.nih.gov/34566077 Zobrazit plný text záznamu