Millimeter-wave time-resolved studies of HCO+-H2 inelastic collisions

Autor: Frank C. De Lucia, Eric Herbst, L. C. Oesterling
Rok vydání: 2001
Předmět:
Zdroj: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 57:705-716
ISSN: 1386-1425
Popis: A novel ion cell has been constructed for the purpose of studying rotationally inelastic collisions involving truly thermal molecular ions at low temperatures. With this ion cell, time-resolved double resonance (pump-probe) spectroscopic experiments have been performed to determine the cross sections for relaxation of the J = 2 state of HCO+ in collisions with normal-H2 at temperatures around 40 and 77 K. The HCO+ is pumped through the J = 2
Databáze: OpenAIRE