Crystallochemical aspects of solid state reactions in mechanically alloyed Al-Cu-Fe quasicrystalline powders
| Autor: | Sergey Kaloshkin, Yu. V. Baldokhin, A.I. Salimon, V.S Tcherdyntsev, E.V. Shelekhov, Alexander M. Korsunsky, T.A. Sviridova |
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| Přispěvatelé: | Inc., Acta Materialia |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Exothermic reaction
Diffraction Materials science Polymers and Plastics Annealing (metallurgy) Metals and Alloys Intermetallic Quasicrystal Electronic Optical and Magnetic Materials Condensed Matter::Materials Science Crystallography Differential scanning calorimetry Chemical engineering Metastability Mössbauer spectroscopy Engineering & allied sciences Ceramics and Composites |
| Popis: | A number of elemental mixtures having initial compositions close to Al65Cu23Fe12 were mechanically alloyed at different energy intensities using a planetary mill. Laboratory X-ray diffraction analysis, differential scanning calorimetry and Mössbauer spectroscopy were used for characterization of the phase and structural state of mechanically alloyed powders after different periods of milling and annealing. Several exothermic effects were found, and these were ascribed to specific solid-state reactions. Quantitative phase analysis was applied in order to identify the mechanism of solid-state reactions taking place in the vicinity of the quasicrystalline phase domain in the Al-Cu-Fe system as a result of mechanical and thermal excitation and homogenization. Metastable intermetallics were identified which possess certain structural and topological elements identical to those found in quasicrystals. © 2001 Acta Materialia Inc. Published by Elsevier Science Ltd. |
| Databáze: | OpenAIRE |
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