Metal-Free Oxidative C(sp3)–H Bond Thiolation of Ethers with Disulfides

Autor:	Jian-nan Xiang, Yan-qin Yuan, Sheng‐rong Guo
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Hydrogen bond Aryl Organic Chemistry Oxidative phosphorylation Biochemistry Peroxide Catalysis chemistry.chemical_compound Metal free chemistry Organic chemistry Physical and Theoretical Chemistry Alkyl
Zdroj:	Organic Letters. 15:4654-4657
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol402281f
Popis:	A novel method for the preparation of alkyl aryl sulfides through direct oxidation thiolation of commercial ethers with diaryl disulfides using di-tert-butyl peroxide (DTBP) as the oxidant without a metal catalyst was established. The C(sp(3))-H bond in various ethers was successfully converted into a C-S bond, and the corresponding sulfides were achieved with moderate to high yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::38d967e8c3324526cd0d3deee915c77a https://doi.org/10.1021/ol402281f Zobrazit plný text záznamu