Synthesis, structure, and electrochemical properties of N,Nʹ-bis(ferrocenylmethylene)ethylenediamine Schiff base and its metal complexes
| Autor: | Tugba Akcan Kardas, Yurdanur Akgül, Funda Demirhan, Hülya Avcı Özbek |
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| Přispěvatelé: | Department of Chemistry, Faculty of Sciences and Liberal Arts, Celal Bayar University, Manisa, Turkey, Department of Chemistry, Faculty of Sciences, Ege University, Bornova-İzmir, Turkey |
| Rok vydání: | 2017 |
| Předmět: |
Schiff base
010405 organic chemistry Metal salts Inorganic chemistry Ethylenediamine 010402 general chemistry Electrochemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound chemistry Ferrocene visual_art Polymer chemistry visual_art.visual_art_medium SN2 reaction Physical and Theoretical Chemistry Cyclic voltammetry |
| DOI: | 10.6084/m9.figshare.5255590 |
| Popis: | The reaction of N,N'-bis(ferrocenylmethylene)ethylenediamine (FcNN) Schiff base with metal salts gave SnCl4FcNN (1), SnCl2FcNN(H2O)2 (2), Sn2(CH3)4Cl4FcNN (3), Ti2Cl8FcNN (4), CdFcNN(NO3)2 (5), and CuFcNN(NO3)2 (6). New complexes (1)–(6) were characterized by IR and elemental analysis techniques. IR spectra showed that the Schiff base was coordinated to the metal ions in a bidentate manner with N,N' donor sites. The 1H NMR spectra of complexes (1), (2), and (4) show all the expected signals with a typical signal pattern of disubstituted ferrocenyl groups. The electrochemical properties of complexes were determined by cyclic voltammetry. Cyclic voltammetry results show that these complexes exhibit one irreversible oxidation peak. |
| Databáze: | OpenAIRE |
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