Poly[[bis{μ3-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)]
| Autor: | Wolfgang Linert, Franz Werner, Kenji Tokuno, Kurt Mereiter, Miki Hasegawa |
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| Rok vydání: | 2010 |
| Předmět: |
Metal-Organic Papers
Tris Tertiary amine biology Chemistry Cationic polymerization chemistry.chemical_element General Chemistry Condensed Matter Physics biology.organism_classification Medicinal chemistry Copper Amine ligands Perchlorate chemistry.chemical_compound Tetra General Materials Science Amine gas treating |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| DOI: | 10.1107/s1600536810008998 |
| Popis: | In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetra-zole N(4) atoms of six symmetry-equivalent tris-[2-(1H-tetra-zol-1-yl)eth-yl]amine ligands (t(3)z) in the form of a Jahn-Teller-distorted octa-hedron with Cu-N bond distances of 2.0210 (8), 2.0259 (8) and 2.4098 (8) Å. The tertiary amine N atom is stereochemically inactive. The cationic part of the structure, viz. [Cu(t(3)z)(2)](2+), forms an infinite two-dimensional network parallel to (100), in pockets of which the perchlorate anions reside. The individual networks are partially inter-locked and held together by C-H⋯O inter-actions to the perchlorate anions and C-H⋯N inter-actions to tetra-zole N atoms. |
| Databáze: | OpenAIRE |
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