Autoionization of SmI3 in Tetrahydrofuran. X-ray Crystal Structure of the Ionic Complex [SmI2(THF)5][SmI4(THF)2]

Autor:	Bo-Mu Wu, Ka-yue Chiu, Zuowei Xie, Thomas C. W. Mak
Rok vydání:	1997
Předmět:	chemistry.chemical_classification Chemistry X-ray Crystal structure Photochemistry Coordination complex Inorganic Chemistry Crystallography chemistry.chemical_compound Autoionization X-ray crystallography Ionic complex Physical and Theoretical Chemistry Tetrahydrofuran
Zdroj:	Inorganic Chemistry. 36:748-748
ISSN:	1520-510X 0020-1669
Popis:	SmI3 can be prepared by the reaction of SmI2 with O2 in dry condition. It crystallizes as an ionic complex, [SmI2(THF)5][SmI4(THF)2], from THF, rather than the simple coordination compound SmI3(THF)3.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::381f867bc6b173513ce06ec62464a0d5 https://doi.org/10.1021/ic961411c Zobrazit plný text záznamu