Self-Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8−

Autor:	Ulrich Kortz, Isabel W. C. E. Arends, Elena V. Chubarova, Maria Mifsud, Louis Nadjo, Bineta Keita, Frédéric Miserque, Michael H. Dickman
Rok vydání:	2008
Předmět:	Molecular Conformation chemistry.chemical_element General Chemistry Tungsten Compounds Photochemistry Electrochemistry Chemical equation Catalysis Arsenic Ion Nanoclusters Crystallography chemistry Cluster (physics) Arsenates Nanoparticles Self-assembly Particle Size Palladium
Zdroj:	Angewandte Chemie International Edition. 47:9542-9546
ISSN:	1521-3773 1433-7851
DOI:	10.1002/anie.200803527
Popis:	(Chemical Equation Presented) Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II 13AsV 8O34(OH) 6]8- has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates.
Databáze:	OpenAIRE
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