Chelated Bisphosphites with a Calix[4]arene Backbone: New Ligands for Rhodium-Catalyzed Low-Pressure Hydroformylation with Controlled Regioselectivity

Autor:	Lorenz Siggel, Michael Röper, Rocco Paciello
Rok vydání:	1998
Předmět:	Molecular model Chemistry Calixarene Organic chemistry Regioselectivity chemistry.chemical_element Chelation General Chemistry Combinatorial chemistry Catalysis Hydroformylation Rhodium
Zdroj:	Angewandte Chemie (International ed. in English). 38(13-14)
ISSN:	1521-3773
Popis:	Extremely high regioselectivities were achieved in the rhodium-catalyzed low-pressure hydroformylation of 1-octene to n-nonanal with chelate bisphosphites that contain a p-tert-butylcalix[4]arene backbone (shown in the picture). It was possible to tailor the structures and ultimately the catalytic properties of these complexes using molecular modeling calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::37d65ff43a91c978c8c8150177c6383a https://pubmed.ncbi.nlm.nih.gov/34182692 Zobrazit plný text záznamu Plný text