| Autor: |
Anja S. Goldmann, Vanessa Trouillet, Markus M. Zieger, Nicolas Zydziak, Cesar Rodriguez-Emmenegger, Corinna M. Preuss, Christopher Barner-Kowollik |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
ACS macro letters. 3(11) |
| ISSN: |
2161-1653 |
| Popis: |
We fuse the surface anchoring abilities of catechols with the rapid ligating nature of thiocarbonyl thio-based hetero-Diels–Alder (HDA) reactions via the synthesis of a new small molecule (HDA-DOPA-Cp) combining a HDA moiety with a catechol. Inspired by the mechanism of strong adhesion of marine mussels, we employed catechols as anchors to attach HDA ligation points to silicon wafers. The latter was exploited to generate a base for the HDA reactions on the surface employing α-cyclopentadiene (Cp) functional polymers such as poly(ethylene glycol)-Cp (PEG-Cp) and poly(trifluoro ethyl methacrylate)-Cp (PTFEMA-Cp) as dienes. By utilizing the fast and efficient HDA chemistry in combination with catechol anchoring groups, a new method for creating functional surfaces was developed. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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