| Popis: |
The practical realization of the scaling up of gas-solid multiphase flow reactors with chemical reactions is hindered by chaotic flow behaviors and complex heat and mass transfers in the reactor. In addition, a law to scale up complex reaction mechanisms in multiphase flow systems has been rarely proposed in the existing literature. Thus, this study aims to investigate the scaling up of the catalytic cracking fluidized bed downer reactor based on the similitude method of chemical reaction performance. Three downer reactor scales with a height of 5, 15, and 30 m, were investigated. To anticipate the behavior of reactive flow, a Eulerian-Eulerian CFD model, two-fluid model, was constructed, which was combined with the kinetic theory of granular flow. A four-lump kinetic model was chosen to represent the mechanism of the catalytic cracking reaction of heavy oil from the pyrolysis of waste plastic. The CFD model accurately predicted the species composition distribution. The scaling law based on the geometric similarity, kinematic similarity, and chemical reaction similarity, was proposed. The catalytic cracking performance similarity of the downer reactor was obtained. With variances in the range of 10% and mean relative absolute error less than 5%, the axial and lateral distributions of chemical performance (heavy oil conversion, gasoline mass fraction, and gasoline selectivity) were found to be extremely similar. |
