Hydrogen-bond driven assembly of a molecular capsule facilitated by supramolecular chelation
| Autor: | John Desper, Christer B. Aakeröy, Arbin Rajbanshi |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
Molecular Structure
Chemistry Hydrogen bond Stereochemistry Phenylalanine Molecular Conformation Metals and Alloys Supramolecular chemistry Aminopyridines Capsule Cavitand Hydrogen Bonding Resorcinols General Chemistry Resorcinarene Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ethers Cyclic Polymer chemistry Materials Chemistry Ceramics and Composites Molecule Chelation Calixarenes |
| Zdroj: | Chemical Communications. 47:11411 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c1cc14124d |
| Popis: | Resorcinarene-based cavitands functionalized with acetamido groups capable of self-complementary hydrogen-bond interactions, were synthesized in order to construct supramolecular capsules. The 1,3-bifunctionalized cavitand produced a polymeric assembly, whereas the tetra-functionalized analogue yielded a discrete capsule held together via N-H···O hydrogen bonds. The ethynyl species attached to the rim of these host molecules deepen each cavitand and expands the volume of the resulting capsule. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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