Polyethylene glycol functionalized graphene oxide and its influences on properties of Poly(lactic acid) biohybrid materials
Autor: | Chi Nhan Ha Thuc, Duy Thanh Tran, Nguyen Dang Mao, Thi Vi Vi Do, Patrick Perré, Hong Gun Kim, Thi Mai Loan Nguyen, Thi Kim Ngan Nguyen, Sang Cheol Ko, Hun Jeong |
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Přispěvatelé: | International University HCMC [Vietnam], International University, Laboratoire de Génie des Procédés et Matériaux - EA 4038 (LGPM), CentraleSupélec, Centre Européen de Biotechnologies et Bioéconomie (CEBB), LANL-CBNU Engineering Institute Korea [Jeonju-si], Chonbuk National University, INSERM UMRS 1178, Nguyen Tat Thanh University [Vietnam] (NTTU) |
Jazyk: | angličtina |
Rok vydání: | 2019 |
Předmět: |
Materials science
Polyethylene glycol Oxide 02 engineering and technology macromolecular substances 010402 general chemistry 01 natural sciences Industrial and Manufacturing Engineering [SPI.MAT]Engineering Sciences [physics]/Materials chemistry.chemical_compound [SPI]Engineering Sciences [physics] stomatognathic system PEG ratio Poly (lactic acid) Thermal stability Composite material Modified graphene oxide Hydrogen bond Mechanical Engineering technology industry and agriculture 021001 nanoscience & nanotechnology equipment and supplies Exfoliation joint 0104 chemical sciences chemistry Mechanics of Materials Ceramics and Composites Surface modification 0210 nano-technology Dispersion (chemistry) Biohybrid materials |
Zdroj: | Composites Part B: Engineering Composites Part B: Engineering, Elsevier, 2019, 161, pp.651-658. ⟨10.1016/j.compositesb.2018.12.152⟩ |
ISSN: | 1359-8368 1879-1069 |
DOI: | 10.1016/j.compositesb.2018.12.152⟩ |
Popis: | International audience; A biohybrid material based on poly(lactic acid)(PLA) incorporated with low contents of polyethylene glycol(PEG) functionalized graphene oxide (GO) was prepared via melting process and their structure, morphology,mechanical performance, and thermal properties were studied in detail. SEM and TEM characterizations confirmedthat the functionalization of GO with PEG (PEGmGO) promoted its exfoliation into thin exfoliated nanosheets,thereby improving the interactions between PEGmGO filler and PLA matrix at interface. FT-IR spectrashowed the presence of strong polar and hydrogen bonding interactions between components in the biohybrid.Mechanical and thermal tests indicated that there was the significant improvement of the stiffness, strength, andthermal stability of such biohybrid material with the addition of 0.3 phr PEGmGO, as compared to pure PLA,PEG-plasticized PLA, PEG-plasticized PLA/GO, and other surveyed PEG-plasticized PLA/PEGmGO biohybrids.This behavior was attributed to the homogeneous dispersion of the PEGmGO nanofillers within PLA matrix alongwith their strong interfacial interaction. The as-obtained biohybrids show highly potential to be useful in thebioengineering applications. |
Databáze: | OpenAIRE |
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